Han Solo

He shot first.

Han Solo is a smuggler working for the Rebel Alliance. He is also captain of the Millenium Falcon. Him and his buddy Chewbacca were recruited by Luke Skywalker to assist them on a trip to Alderaan, and he ended up playing a pivotal role in the Galactic Civil War.

He also married Princess Leia and became a General in the Rebel Alliance and later the New Republic.